BIS(ETHYLCYCLOPENTADIENYL) RUTHENIUM
Bis(ethylcyclopentadienyl)ruthenium(II)
CAS: 32992-96-4
Molecular Formula: C14H10Ru
BIS(ETHYLCYCLOPENTADIENYL) RUTHENIUM - Names and Identifiers
| Name | Bis(ethylcyclopentadienyl)ruthenium(II) |
| Synonyms | ETHYL RUTHENOCENE DIETHYLRUTHENOCENE BIS(ETHYLCYCLOPENTADIENYL) RUTHENIUM Bis(ethylcyclopentadienyl)ruthenium(II) BIS(ETHYLCYCLOPENTADIENYL)RUTHENIUM(II) |
| CAS | 32992-96-4 |
| InChIKey | HXJQELBDFQFTHS-UHFFFAOYSA-N |
BIS(ETHYLCYCLOPENTADIENYL) RUTHENIUM - Physico-chemical Properties
| Molecular Formula | C14H10Ru |
| Molar Mass | 279.3 |
| Density | 1.3412 g/mL at 25 °C (lit.) |
| Melting Point | 6 °C (lit.) |
| Boling Point | 100 °C/0.01 mmHg (lit.) |
| Flash Point | >200°F |
| Appearance | liquid |
| Specific Gravity | 1.341 |
| Color | pale yellow |
| Storage Condition | -20°C |
| Sensitive | 4: no reaction with water under neutral conditions |
| Refractive Index | n20/D 1.5870(lit.) |
BIS(ETHYLCYCLOPENTADIENYL) RUTHENIUM - Risk and Safety
| Hazard Symbols | Xi - Irritant |
| Risk Codes | R14/15 - R36/37/38 - Irritating to eyes, respiratory system and skin. |
| Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S43 - In case of fire use ... (there follows the type of fire-fighting equipment to be used.) |
| UN IDs | UN 3398 4.3/PG 2 |
| WGK Germany | 3 |
| TSCA | No |
BIS(ETHYLCYCLOPENTADIENYL) RUTHENIUM - Introduction
Bis(ethylcyclopentadienyl)ruthenium(II) is a metal organic compound with the formula [(C2H5C5H4)2Ru]. The following is an introduction to its nature, use, formulation and safety information:
Nature:
- Bis(ethylcyclopentadienyl)ruthenium(II) is a gray solid, soluble in organic solvents such as diethyl ether, toluene and tetrahydrofuran.
-It is stable in the air, but it is easily decomposed by moisture and oxygen.
-It has high thermal and chemical stability.
Use:
- Bis(ethylcyclopentadienyl)ruthenium(II) is often used as a catalyst in organic synthesis, especially in asymmetric synthesis.
-It can be used for catalytic hydrogenation reaction, oxidation reaction, olefin cyclization reaction and stereoselective hydrocarbon chemical reaction.
Preparation Method:
- Bis(ethylcyclopentadienyl)ruthenium(II) can be prepared by reacting cyclopentadiene with ruthenium(II) chloride in diethyl ether or toluene, and then reacting with vinyl aluminum chloride in tetrahydrofuran.
Safety Information:
- Bis(ethylcyclopentadienyl)ruthenium(II) is generally a low-toxic substance under normal operating conditions, but laboratory safety procedures should still be followed.
-It is irritating to the skin and eyes, so be careful to avoid contact with the skin and eyes.
-During use or handling, it is necessary to avoid dust and particle sputtering to prevent inhalation or ingestion.
- Bis(ethylcyclopentadienyl)ruthenium(II) should be stored in a dry, cool place, away from ignition and oxidizing agents.
Nature:
- Bis(ethylcyclopentadienyl)ruthenium(II) is a gray solid, soluble in organic solvents such as diethyl ether, toluene and tetrahydrofuran.
-It is stable in the air, but it is easily decomposed by moisture and oxygen.
-It has high thermal and chemical stability.
Use:
- Bis(ethylcyclopentadienyl)ruthenium(II) is often used as a catalyst in organic synthesis, especially in asymmetric synthesis.
-It can be used for catalytic hydrogenation reaction, oxidation reaction, olefin cyclization reaction and stereoselective hydrocarbon chemical reaction.
Preparation Method:
- Bis(ethylcyclopentadienyl)ruthenium(II) can be prepared by reacting cyclopentadiene with ruthenium(II) chloride in diethyl ether or toluene, and then reacting with vinyl aluminum chloride in tetrahydrofuran.
Safety Information:
- Bis(ethylcyclopentadienyl)ruthenium(II) is generally a low-toxic substance under normal operating conditions, but laboratory safety procedures should still be followed.
-It is irritating to the skin and eyes, so be careful to avoid contact with the skin and eyes.
-During use or handling, it is necessary to avoid dust and particle sputtering to prevent inhalation or ingestion.
- Bis(ethylcyclopentadienyl)ruthenium(II) should be stored in a dry, cool place, away from ignition and oxidizing agents.
Last Update：2024-04-10 22:29:15
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